Ternary diffusion coefficients of diethanolamine and N-methyldiethanolamine in aqueous solutions containing diethanolamine and N-methyldiethanolamine

Ternary diffusion coefficients of diethanolamine (DEA) and N-methyldiethanolamine (MDEA) in aqueous solutions containing DEA and MDEA using the Taylor dispersion technique have been measured for temperatures (303.2, 313.2, and 323.2 K). The systems studied were aqueous solutions containing total amine concentrations of 2.5 and 4.0 kmol m⁻³, each having four different amine molar ratios. The density and viscosity of the blended amine solutions were also measured. The mutual diffusion coefficients of aqueous DEA and aqueous MDEA solutions were also reported. The main diffusion coefficients (D₁₁ and D₂₂) and the cross-diffusion coefficients (D₁₂ and D₂₁) were reported as function of temperature and concentration of alkanolamines. The limiting conditions for the main diffusion coefficients and the cross-diffusion coefficients were discussed at first, and a comparison between the ratios of the cross-diffusion coefficients to the main diffusion coefficients for DEA and MDEA was made. The dependence of the main diffusion coefficients on the viscosity of solutions was also investigated.