Vapor pressures and flash points for binary mixtures of tricyclo [5.2.1.0] decane and dimethyl carbonate |
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Authors: | Yan Xing Dongbei ShaoWenjun Fang Yongsheng GuoRuisen Lin |
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Institution: | Department of Chemistry, Zhejiang University, Hangzhou 310027, China |
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Abstract: | Bubble-point vapor pressures, equilibrium temperatures and flash points for binary mixtures of a high energy density hydrocarbon fuel, tricyclo 5.2.1.02.6] decane (JP-10), and dimethyl carbonate (DMC) were measured. Correlation between vapor pressures and equilibrium temperatures for each mixture was given by the Antoine equation. The binary system of JP-10 and DMC appears with very large positive deviations of vapor pressure from the Raoult's law. The experimental vapor pressures are correlated and the flash points are then predicted using Scatchard-Hildeband, Van Laar and Wilson models of liquid phase activity coefficients with satisfactory results. |
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Keywords: | High energy density Tricyclo [5 2 1 02 6] decane Dimethyl carbonate Vapor pressure Flash point |
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