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Synthese und Eigenschaften linearer Phosphorylchlorphosphazene
Authors:L Riesel  R Somieski
Abstract:Synthesis and Properties of Lineary Phosphorylchlorphosphazenes The phosphorylchlorphosphazenes, Cl2(O)P—N?PCl2]n—Cl, (n = 1, 2, 3) react like POCl3 with hexamethyldisilazan forming silylamides, Cl2(O)P—N ? PCl2]n—NHSi(CH3)3, (n = 0, 1, 2, 3). From these are obtained the phosphorylchlorphosphazenes by reaction with PCl5 containing one group —N ? PCl2 more.
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