Abstract: | Synthesis and Properties of Lineary Phosphorylchlorphosphazenes The phosphorylchlorphosphazenes, Cl2(O)P—N?PCl2]n—Cl, (n = 1, 2, 3) react like POCl3 with hexamethyldisilazan forming silylamides, Cl2(O)P—N ? PCl2]n—NHSi(CH3)3, (n = 0, 1, 2, 3). From these are obtained the phosphorylchlorphosphazenes by reaction with PCl5 containing one group —N ? PCl2 more. |