Crystal and molecular structures of 1-isoquinolyl(phenyl)methyl benzoate and 1-isoquinolylisopropyl benzoate |
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Authors: | Ewa Skrzypczak-Jankun Andrzej Hoser Elżbieta Grzesiak Zygmunt Kałuski Maria D Rozwadowska |
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Institution: | (1) Institute of Chemistry, A. Mickiewicz University, Grunwaldzka 6, 60-780 Pozna , Poland |
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Abstract: | Both of the title compounds crystallize in the monoclinic system: C23H17NO2 (Ib),P21/c,a = 8.970(1),b = 22.629(5),c = 9.101(1) Å, = 106.08(1) °,Z = 4,D
x
= 1.27 Mg m–3; C19H17NO2 (Ic),P21/a,a = 15.225(2),b = 6.429(1),c = 17.190(1) Å, = 112.99(1) °,Z = 4,D
x
= 1.25 Mg m–3. The structures were solved and refined by standard methods, both toR 0.04. In compound Ib, a weak intramolecular interaction is observed between the nitrogen atom from the isoquinoline ring and the carbon atom from the carbonyl group, with the N(2) . C(18)distance being 2.98 Å. In compound Ic, the PhCO2 -fragment is twisted in the opposite direction to that in compound Ib, without hydrogen bonding. The pK
a
and IR data were considered in the light of the results of the X-ray investigation. |
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