Antimony(III) Complexes with Quaternary Ammonium Bases: Synthesis, Spectral, and Luminescent Properties |
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| Authors: | N. V. Petrochenkova T. V. Storozhuk A. G. Mirochnik V. E. Karasev |
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| Affiliation: | (1) Far East Division, Russian Academy of Sciences, Institute of Chemistry, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia |
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| Abstract: | Complexes of antimony(III) halides with quaternary ammonium bases of different composition were synthesized and characterized by elemental and X-ray diffraction analyses and IR and luminescence spectroscopy. For complexes [R"3R"N]SbHal4 (Hal = Cl–, Br–, R" = R" = CH3, C2H5, C4H9), the maximum of the emission band and fluorescence intensity was found to depend on the nature of the halide ion and the alkyl radical length. |
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