| Synthesis, Characterization and Crystal Structure of [Na2(APZC)2(μ-H2O)2(μ3-H2O)]n |
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| 引用本文： | TAYEBEE Reza,AMANI Vahid,KHAVASI Hamid Reza. Synthesis, Characterization and Crystal Structure of [Na2(APZC)2(μ-H2O)2(μ3-H2O)]n[J]. 中国化学, 2008, 26(3): 500-504. DOI: 10.1002/cjoc.200890094 |
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| 作者姓名： | TAYEBEE Reza AMANI Vahid KHAVASI Hamid Reza |
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| 作者单位： | Department of Chemistry, Sabzevar University, Sabzevar, Iran Research Institute of Education, 16 Hojjat Dost Street, Vessal Shirazi Avenue, Tehran, Iran Department of Chemistry, Shahid Beheshti University, Tehran, Iran |
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| 摘 要： | The synthesis and spectroscopic properties of a Na＋ complex with ligand 3-aminopyrazine-2-carboxylic acid were described. The resulting complex was characterized by elemental analysis, IR, UV-Vis, NMR spectroscopy and single crystal X-ray diffraction method. The title compound crystallizes in the triclinic system with space group . The crystalline structure of this compound consists of supramolecular architectures involving strong intramolecular N—H…O in pyrazine molecules and intermolecular O—H…N, O—H…O, and N—H…N hydrogen bonds between substituted pyrazine and water molecules.
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| 关 键 词： | structure 3-aminopyrazine-2-carboxylic acid sodium complex |
| 收稿时间： | 2007-09-27 |
| 修稿时间： | 2007-11-13 |
Supramolecular Architecture from a Sodium Coordination Polymer with a 3D Net Containing 3‐Aminopyrazine‐2‐carboxylic acid (APZC):Synthesis,Characterization and Crystal Structure of [Na2(APZC)2(μ‐H2O)2(μ3‐H2O)]n |
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| Reza TAYEBEE,Vahid AMANI,Hamid Reza KHAVASI. Supramolecular Architecture from a Sodium Coordination Polymer with a 3D Net Containing 3‐Aminopyrazine‐2‐carboxylic acid (APZC):Synthesis,Characterization and Crystal Structure of [Na2(APZC)2(μ‐H2O)2(μ3‐H2O)]n[J]. Chinese Journal of Chemistry, 2008, 26(3): 500-504. DOI: 10.1002/cjoc.200890094 |
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| Authors: | Reza TAYEBEE Vahid AMANI Hamid Reza KHAVASI |
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| Affiliation: | 1. Research Institute of Education, 16 Hojjat Dost Street, Vessal Shirazi Avenue, Tehran, Iran;2. Department of Chemistry, Shahid Beheshti University, Tehran, Iran |
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| Abstract: | The synthesis and spectroscopic properties of a Na+ complex with ligand 3‐aminopyrazine‐2‐carboxylic acid were described. The resulting complex was characterized by elemental analysis, IR, UV‐Vis, NMR spectroscopy and single crystal X‐ray diffraction method. The title compound crystallizes in the triclinic system with space group . The crystalline structure of this compound consists of supramolecular architectures involving strong intramolecular N–H···O in pyrazine molecules and intermolecular O–H···N, O–H···O, and N–H···N hydrogen bonds between substituted pyrazine and water molecules. |
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| Keywords: | structure 3‐aminopyrazine‐2‐carboxylic acid sodium complex |
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