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Influence of interparticle interaction effects on the rheological properties of low density polyethylene filled with glass beads
Institution:1. Institute for Polymer Technologies e. V., 23966 Wismar, Germany;2. Department of Mechanical Engineering, Hochschule Wismar University of Applied Sciences, Technology, Business and Design, 23966 Wismar, Germany;3. Department of Plastics Technologies, Ilmenau University of Technology, 98693 Ilmenau, Germany;1. The Key Laboratory of Polymer Processing Engineering, Ministry of Education, South China University of Technology, Guangzhou 510640, China;2. Research and Development Department, Zhejiang Zhongning Silicon Company Ltd, QuZhou 324000, China;3. School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China;1. MMRI/ CAPPA-D, Department of Chemical Engineering, McMaster University, Hamilton, Ontario L8S 4L7, Canada;2. 3M Canada Company, London, Ontario, Canada;1. College of Materials Science and Engineering, Shenzhen Key Laboratory of Polymer Science and Technology, Guangdong Research Center for Interfacial Engineering of Functional Materials, Nanshan District Key Lab for Biopolymers and Safety Evaluation, Shenzhen University, Shenzhen 518060, PR China;2. Key Laboratory of Optoelectronic Devices and System of Ministry Education and Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, PR China;1. Technische Universität Dresden, Institut für Leichtbau und Kunststofftechnik, 01062 Dresden, Germany;2. Technische Universität Dresden, Institut für Magnetofluiddynamik, Mess- und Automatisierungstechnik, 01062 Dresden, Germany;3. Anton Paar GmbH, Ostfildern-Scharnhausen, 73760, Germany
Abstract:The rheological properties of Low-density polyethylene (LDPE) compounds with different fractions of glass beads have been investigated by means of high pressure capillary rheometry. The purpose of this study is to find a functional approach for describing the flow behaviour of suspensions as a function of the volumetric filler content and the applied shear stress or shear rate, respectively. The flow behaviour of suspensions is influenced by interaction effects, which are dependent on the filler particle, its volume content and particle size. While small glass beads exhibit pronounced interparticle interaction effects even at low volumetric filler concentrations, large glass beads show a plateau of negligibly interactions up to approx. 20% volumetric filler content. With introducing a generalized interaction function the flow behaviour of the tested suspensions could be described with reasonable accuracy in consideration of the transition from negligible to pronounced interactions.
Keywords:High pressure capillary rheometry  Rheology  Interaction effects  Generalized interaction function  Glass beads  Suspension
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