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Influence of liquefied wood polyol on the physical-mechanical and thermal properties of epoxy based polymer
Institution:1. Department of Forestry and Wood Technology, Faculty of Technology, Linnaeus University, Lückligs Plats 1, 35195 Växjö, Sweden;2. Czech Technical University in Prague, Faculty of Civil Engineering, Department of Building Structures, Thákurova 7, 166 29 Prague 6, Czech Republic;3. Slovenian National Building and Civil Engineering Institute, Dimičeva 12, SI-1000 Ljubljana, Slovenia;4. Jožef Stefan Institute, Jamova 39, SI-1000 Ljubljana, Slovenia;5. University of Ljubljana, Biotechnical Faculty, Department of Wood Science and Technology, Jamnikarjeva, 101, 1000 Ljubljana, Slovenia;1. International and Inter University Centre for Nanoscience and Nanotechnology, Mahatma Gandhi University, Kottayam, Kerala 686560, India;2. School of Chemical Sciences, Mahatma Gandhi University, Kottayam, Kerala 686560, India;3. Department of Physics, Birla Institute of Technology & Science, Pilani, Hyderabad 500078, India;4. Normandie Univ, UNIROUEN Normandie, INSA Rouen, CNRS, Groupe de Physique des Matériaux, 76000 Rouen, France;5. Department of Soil, Plant and Food Sciences, University of Bari “Aldo Moro”, Via Amendola 165/A, 70126 Bari, Italy;6. School of Pure and Applied Physics, Mahatma Gandhi University, Kottayam, Kerala 686560, India;1. Lab of Advanced Elastomer, South China University of Technology, Guangzhou, 510640, China;2. The Key Laboratory of Polymer Processing Engineering, Ministry of Education, China (South China University of Technology), Guangzhou, 510640, China;3. College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China;4. State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu, 610065, China;1. LabMAT, Department of Civil and Environmental Engineering, University of Bío-Bío, 4051381 Concepción, Chile;2. Department of Mechanical Engineering, University of the Basque Country, 48013 Bilbao, Spain;1. School of Engineering, Trinity College Dublin, College Green, Dublin 2, Ireland;2. Centre for Innovative Human Systems, Trinity College Dublin, College Green, Dublin 2, Ireland
Abstract:Epoxy resins are mostly produced from petroleum-based bisphenol A and epicholorhydrin. Bisphenol A is synthesized from non-renewable petroleum-based phenol and acetone. Biomass derived epoxy-based polymers (EBPs) are becoming the most promising alternative for petroleum-based counterparts, but still these biomass-based EBPs have inferior properties. In the present work, two types of epoxy resins were prepared with different weight percentages of resin (bisphenol A) and hardener. They were then modified with different weight percentages of liquefied wood from spruce sawdust. The derived EBPs were analysed in terms of tensile strength and tensile modulus, fractured surface morphology, thermal stability, long-term water adsorption and resistance to brown-rot fungus decay. The results revealed that the percentages of hardener and liquefied wood significantly influenced the overall properties of the EBPs.
Keywords:Liquefied wood  Epoxy based polymer  Tensile properties  Thermo-mechanical properties
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