Hydrogenation of Olefins Catalyzed by a Cobalt(I) Hydride Complex with N-Heterocyclic Silylene |
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| Authors: | Hongwei Jia Shaozhi Du Dr. Chuangchuang Xu Prof. Dr. Zhenbo Mo |
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| Affiliation: | State Key Laboratory and Institute of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University, Tianjin, 300071 China |
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| Abstract: | Herein, we report the synthesis, characterization, and reactivity of the cobalt(I) complexes with an N-heterocyclic imino substituted silylene. The cobalt(I) hydride complex exhibits high catalytic efficiency and chemoselectivity as well as good functional group compatibility in the hydrogenation of olefins. |
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| Keywords: | cobalt chemoselectivity hydride hydrogenation N-heterocyclic silyene |
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