Magnetic coupling and intermetallic electron transfer in the heterodinuclear bioctahedral complexes MW(III)Cl(9)(n-) (M = V(II), Cr(III), Mn(IV)): tweaking the balance between ferromagnetism and antiferromagnetism |
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Authors: | Petrie Simon Stranger Robert |
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Affiliation: | Department of Chemistry, The Faculties, The Australian National University, Canberra ACT 0200, Australia. |
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Abstract: | Density functional theory (DFT) calculations have been used to investigate the effect of intermetallic electron transfer on the mode of magnetic coupling in the face-shared bimetallic complexes MWCl(9)(n-) (M = V, Cr, Mn; all with a nominal d(3) valence electronic configuration on each metal atom). These calculations illustrate a simple rule: when the oxidation state of M is lower than that of W, antiferromagnetic coupling is preferred, while ferromagnetism (via crossed exchange pathways) is favored when M has the higher oxidation state. This underlying trend in intermetallic interactions is seen to depend on the interplay among ligand field splitting, spin polarization splitting of alpha- and beta-spin orbitals, and the relative energies of the M and W valence d orbitals, and is mirrored in the results seen in a wider survey of mixed-metal, face-shared complexes. |
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