Synthesis of substituted 1,3-thiazinoazoles |
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Authors: | N D Abramova L V Andriyankova Yu M Skvortsov A G Mal'kina é I Kositsyna A I Albanov G G Skvortsova |
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Institution: | (1) Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, 664033 Irkutsk |
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Abstract: | Substituted 1,3-thiazinoazoles were obtained by treating benzimidazole-2-thione, 4,5-diphenylimidazole-2-thione, and 1,2,4-triazole-3-thione with tertiary cyanoacetylenic alcohols and their acetals in the presence of lithium hydroxide. Treatment of the 1,3-thiazinobenzimidazoles with base destroyed the thiazino ring forming benzimidazol-2-one.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1412–1415, October, 1986. |
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