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Cobalt carbaporphyrin-catalyzed cyclopropanation
Authors:Fields Kimberly B  Engle James T  Sripothongnak Saovalak  Kim Chungsik  Zhang X Peter  Ziegler Christopher J
Affiliation:Department of Chemistry, University of South Florida, Tampa, FL 33620-5250, USA.
Abstract:Cobalt complexes of N-confused porphyrins and benziphthalocyanine, which both feature organometallic bonds at the macrocycle cores, catalyze the cyclopropanation of styrene with a higher trans-selectivity than the corresponding porphyrin and phthalocyanine complexes.
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