Cobalt carbaporphyrin-catalyzed cyclopropanation |
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Authors: | Fields Kimberly B Engle James T Sripothongnak Saovalak Kim Chungsik Zhang X Peter Ziegler Christopher J |
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Affiliation: | Department of Chemistry, University of South Florida, Tampa, FL 33620-5250, USA. |
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Abstract: | Cobalt complexes of N-confused porphyrins and benziphthalocyanine, which both feature organometallic bonds at the macrocycle cores, catalyze the cyclopropanation of styrene with a higher trans-selectivity than the corresponding porphyrin and phthalocyanine complexes. |
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