Density Functional Study on the Mechanism of Amadori Rearrangement Reaction |
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| Authors: | BAO Xiu-Xiu CHEN Zu-Qin XIE Hu-Jun |
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| Institution: | Department of Applied Chemistry, School of Food Science and Biotechnology, Zhejiang Gongshang University, Hangzhou 310035, China |
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| Abstract: | The reaction mechanism of amadori rearrangement in the initial stage of Maillard reaction has been investigated by means of density functional theory calculations in the gaseous phase and aqueous solution.Cyclic ribose and glycine were taken as the model in the amadori rearrangement.Reaction mechanisms have been proposed,and possibility for the formation of different compounds has been evaluated through calculating the relative energy changes for different steps of the reaction by following the total mass b... |
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| Keywords: | DFT calculations amadori rearrangement reaction interstellar medium maillard reaction |
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