Preparation and operating conditions for cobalt cerium oxide catalysts used in the conversion of synthesis gas into light olefins

Cobalt cerium oxides, prepared using a co-precipitation procedure, were studied as catalysts for the conversion of synthesis gas to light olefins (C₂-C₄). Specifically, we studied the effect of a range of preparation variables, including the molar ratio of the Co]/Ce] of the precipitation solution, ageing time and calcination temperature. In addition, the effects of supports and promoters on the catalysts’ activity and selectivity and a range of reaction temperatures using synthesis gas with different H₂/CO molar feed ratios were investigated. The catalyst containing a molar ratio of 80% Co and 20% Ce, aged for 2 h, supported with 15 wt% SiO₂ without any promoter, at an operating temperature of 450 °C and an H₂/CO feed ratio of 2/1 (GHSV = 4500 h^?1), performed optimally for the conversion of synthesis gas to light olefins. The characterization of both the precursors and the calcined catalysts by powder X-ray diffraction, scanning electron microscopy, Brunauer-Emmett-Teller specific surface area measurements and thermal analysis methods, including TGA and DSC, show that all the preparation variables influenced the catalyst precursor structure.