Palladium-catalyzed selective acyloxylation using sodium perborate as oxidant |
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| Authors: | Pilarski Lukasz T Janson Pär G Szabó Kálmán J |
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| Affiliation: | Department of Organic Chemistry, Stockholm University, Arrhenius Laboratory, SE-10691 Stockholm, Sweden. |
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| Abstract: | Sodium perborate (SPB), a principal component of washing powders, was employed as an inexpensive and eco-friendly oxidant in the palladium-catalyzed C-H acyloxylation of alkenes in excellent regio- and stereochemistry. The reactions used anhydrides as acyloxy sources. The method applies to both terminal and internal alkenes, and even benzylic C-H oxidation. |
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