Enantiospecific synthesis of (?)-2-hydroxy-exo-brevicomin |
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| Institution: | 1. Key Laboratory for Green Chemistry Process of Ministry of Education, School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430073, PR China;2. Department of Chemistry, Central China Normal University, Wuhan 430079, PR China |
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| Abstract: | An enantiospecific synthesis of (?)-2-hydroxy-exo-brevicomin was achieved from l-(+)-tartaric acid in high yield. The key step involves a very highly diastereoselective reduction of a keto Weinreb amide. |
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