Inclusion of cyclic carbonates by a cholic acid host: structure and enantioselection |
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| Affiliation: | 1. Dipartimento di Chimica, Università di Ferrara, Via Borsari 46, 44100 Ferrara, Italy;2. Dipartimento di Chimica, Università della Calabria, Via Bucci 12C, 87036 Rende CS, Italy;1. Department of Physical Chemistry, University of Chemistry and Technology, Prague, Technická 5, CZ-166 28 Prague 6, Czech Republic;2. UMR 5615, Université de Lyon-UCB Lyon1, 43 bd du 11 Novembre 1918, 69622 Villeurbanne, France;3. Université de Saint Etienne, Jean Monnet, F-42023 Saint Etienne, France;4. Department of Semiconductors, Institute of Physics, Academy of Sciences of the Czech Republic, v. v. i., Cukrovarnická 10, CZ-162 00 Prague 6, Czech Republic;1. Faculty of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China;2. School of Material Science and Engineering, Jiangsu University, Zhenjiang 212013, China;1. Universidade Federal Fluminense, Instituto de Química, Departamento de Química Orgânica, CEG, Campus do Valonguinho, 24020-141 Niterói, Rio de Janeiro, Brazil;2. Universidade Federal do Rio de Janeiro, Instituto de Química, Ilha do Fundão, Centro de Tecnologia, Bloco A, 21949-900 Rio de Janeiro, Brazil;1. School of Pharmacy, Monash University Malaysia, Jalan Lagoon Selatan, Bandar Sunway, Selangor Darul Ehsan 47500, Malaysia;2. School of Pharmacy, Curtin Health Innovation Research Institute, Curtin University, GPO Box U1987, Perth, Western Australia 6845, Australia;1. Universidad de Vigo, Departamento de Física Aplicada, Edificio Manuel Martínez Risco, Campus del Agua, 32004 Ourense, Spain;2. Laboratorio Oficial de Metroloxía de Galicia (Consellería de Economía, Emprego e Industria), Av. de Galicia 1,3, Parque Tecnolóxico de Galicia, San Ciprián de Viñas, 32901 Ourense, Spain |
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| Abstract: | The optical resolution of some model monosubstituted cyclic carbonates, by inclusion in cholic acid, is described. The X-ray analysis of the host–guest crystal structures provide a rationale for molecular recognition. |
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