Asymmetric hydrogenation of the C–C double bond of 1- and 1,2-methylated maleimides with cultured suspension cells of Marchantia polymorpha |
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| Institution: | 1. Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526, Japan;2. Graduate School of Pharmaceutical Science, The University of Tokushima, 1-78 Shomachi, Tokushima 770-8505, Japan;1. Department of Chemistry, College of Science, Engineering and Technology, University of South Africa, PO Box 392, Pretoria 0003, South Africa;2. Computational Chemistry Group, Department of Chemistry, Faculty of Science, University of Mauritius, Réduit 80837, Mauritius;1. Departamento de Química Orgánica I, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Ciudad Universitaria s/n, 28040, Madrid, Spain;2. Departamento de Química Física, Universidad del País Vasco-EHU, Apartado 644, 48080, Bilbao, Spain;3. Sección Departamental de Química Orgánica I, Facultad de Óptica y Optometría, Universidad Complutense de Madrid, Arcos de Jalón 118, 28037, Madrid, Spain;4. Departamento de Sistemas de Baja Dimensionalidad, Superficies y Materia Condensada, Instituto de Química-Física “Rocasolano”, CSIC, Serrano 119, 28006, Madrid, Spain |
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| Abstract: | Suspension cultured cells of Marchantia polymorpha have the potential to hydrogenate the C–C double bonds of 2-methyl- and 2,3-dimethylmaleimide derivatives to give enantiomerically pure (2R)-2-methyl- and (2R,3R)-2,3-dimethylsuccinimide derivatives, respectively. |
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