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Effect of equilibrium and dynamic surface activity of surfactant on foam transport in porous medium
Affiliation:1. Department of Chemical and Pharmaceutical Engineering, Faculty of Chemistry and Pharmacy, Sofia University, 1 J. Bourchier Ave., 1164 Sofia, Bulgaria;2. Unilever R&D, Port Sunlight, Quarry Road East, Bebington, Wirral CH63 3JW, UK;3. Unilever R&D, Vlaardingen, the Netherlands;4. Laboratory of Physical Chemistry and Colloid Science, Wageningen University, 6703 HB Wageningen, the Netherlands;5. Department of Mechanical Engineering, University College London, Torrington Place, London WC1E 7JE, UK
Abstract:An apparatus containing a visual porous medium plate model and digital video recorder was employed to investigate the transportation of foam stabilized by sodium polyoxyethylene alkylether sulfate (AES), sodium dodecyl benzene sulfonate (SDBS) and TritonX-100 in porous medium. The results showed that transfiguration and fracture were the main transport manners for foam in the porous medium at high gas and liquid transfusion rate. The increase in probability of transfiguration in foam transport process corresponded to the higher flow impedance. A simple U-shape device was designed to investigate the rigidity of surfactant layer at the gas/liquid interface, and the equilibrium surface tension was assigned to be the key parameter which manifests the rigidity of surfactant interface layer. The dynamic surface tension of different surfactant system has also been measured, and the parameters gotten by Rosen model might be the measurement of dynamic elasticity of surfactant interface layer. There is consanguineous relation between the equilibrium surface activity or dynamic activity of the surfactants and the transport of the foam in the porous medium.
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