Asymmetric 1,4-addition of aryltrialkoxysilanes to α,β-unsaturated esters and amides catalyzed by a chiral rhodium complex |
| |
| Institution: | 1. Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong;2. Department of Chemistry, Faculty of Science, Kyoto University, Japan;1. Department of Inorganic Chemistry, University of Madras, Guindy Campus, Chennai, India;2. ITC Life Sciences and Technology Centre, ITC Limited, Peenya Industrial Area, Phase I, Bangalore, India;1. Department of Chemistry, Innovative Drug Research Center, Shanghai University, Shanghai 200444, PR China;2. Laboratory for Microstructures, Instrumental Analysis and Research Center of Shanghai University, Shanghai 200444, PR China;3. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, PR China;4. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, PR China;1. Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, C/Marcel·li Domingo, s/n. 43007 Tarragona, Spain;2. CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France;3. Université de Toulouse, INPT, UPS, Toulouse, France;4. Institut Universitaire de France, 103, bd Saint-Michel, 75005 Paris, France;1. Department of Organic Chemistry, Faculty of Pharmacy, Medical University of Warsaw, Banacha 1, 02 097 Warsaw, Poland;2. Department of Crystallography, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60 780 Poznań, Poland;3. Department of Histology and Embryology, First Faculty of Medicine, Medical University of Warsaw, Chałubiński 5, 02 004 Warsaw, Poland;1. Bio-Organic and Photochemistry Laboratory, Department of Pharmaceutical Sciences, Guru Nanak Dev University, Amritsar 143 005, Punjab, India;2. Forensic Science Laboratory, Mohali, Punjab, India;3. Department of Physics & Electronics, University of Jammu, Jammu Tawi 180 006, India |
| |
| Abstract: | A highly enantioselective 1,4-addition of aryltrialkoxysilanes to α,β-unsaturated esters and amides was successfully catalyzed by a chiral rhodium complex generated from Rh(cod)(MeCN)2]BF4 and (S)-BINAP. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
