Enantioselective synthesis induced by tetrathia-[7]-helicenes in conjunction with asymmetric autocatalysis |
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| Affiliation: | 1. School of Chemical Sciences, KBC North Maharashtra University, Jalgaon 425001, India;2. University Institute of Chemical Technology, KBC North Maharashtra University, Jalgaon 425001, India;3. Vasantrao Naik Arts, Science and Commerce College Dharni, Amravati 444702, India;4. KVPS''s Kisan Arts, Commerce and Science College, Parola, Jalgaon 425111, India;1. Laboratory of asymmetric synthesis and molecular engineering of organic materials for electronic organics (LR18ES19), Monastir Faculty of Sciences, University of Monastir, Monastir 5019, Tunisia;2. Department of Chemistry, University College Alwajh, University of Tabuk, Tabuk 71421, Saudi Arabia;3. Laboratory of Interfacial and Advanced Materials, Monastir Faculty of Sciences, University of Monastir, Monastir 5019, Tunisia |
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| Abstract: | Highly enantioenriched 5-pyrimidyl alkanol was formed using tetrathia-[7]-helicenes as a chiral initiator in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, in conjunction with asymmetric autocatalysis. |
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