| CuPc(COOH)8-SA/CuTAPc-CS双极膜的制备及表征 |
| |
| 引用本文： | 陈日耀,陈震,郑曦,陈晓,倪世茂,尤春满. CuPc(COOH)8-SA/CuTAPc-CS双极膜的制备及表征[J]. 高等学校化学学报, 2010, 31(3): 530 |
| |
| 作者姓名： | 陈日耀 陈震 郑曦 陈晓 倪世茂 尤春满 |
| |
| 作者单位： | 1. 福建师范大学化学与材料学院, 福州 350007; 2. 宁德师范高等专科学校化学系, 宁德 352100 |
| |
| 基金项目： | 福建省自然科学基金(批准号:D0710009)资助 |
| |
| 摘 要： | 分别用八羧基铜酞菁[CuPc(COOH)8]和四氨基铜酞菁(CuTAPc)改性海藻酸钠(SA)阳膜层和壳聚糖(CS)阴膜层, 制备了CuPc(COOH)8-SA/CuTAPc-CS双极膜. 实验结果表明, 经八羧基铜酞菁和四氨基铜酞菁改性后, 促进了双极膜中间层水的解离, 增大了阳离子交换膜层和阴离子交换膜层的离子交换容量及H+和OH-的透过率. 与Fe3+改性的Fe-SA/mCS双极膜相比, CuPc(COOH)8-SA/CuTAPc-CS双极膜的阻抗、电阻压降(即IR降)和溶胀度降低. 当电流密度高达120 mA/cm2时, CuPc(COOH)8-SA/CuTAPc-CS双极膜的IR降仅为0.9 V.
|
| 关 键 词： | 八羧基铜酞菁 四氨基铜酞菁 海藻酸钠 壳聚糖 双极膜, |
| 收稿时间： | 2009-08-06 |
Preparation and Characterization of CuPc(COOH)_8-SA/CuTAPc-CS Bipolar Membrane |
| |
| CHEN Ri-Yao,CHEN Zhen,ZHENG Xi,CHEN Xiao,NI Shi-Mao,YOU Chun-Man. Preparation and Characterization of CuPc(COOH)_8-SA/CuTAPc-CS Bipolar Membrane[J]. Chemical Research In Chinese Universities, 2010, 31(3): 530 |
| |
| Authors: | CHEN Ri-Yao CHEN Zhen ZHENG Xi CHEN Xiao NI Shi-Mao YOU Chun-Man |
| |
| Affiliation: | 1. College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China;2. Chemistry Department of Fujian Ningde Teachers College, Ningde 352100, China |
| |
| Abstract: | The sodium alginate(SA) cation layer and the chitosan(CS) anion layer were modified by copper octocarboxyphthalocyanine[CuPc(COOH)8] and copper tetraaminophthalocyanine(CuTAPc) to prepare the CuPc(COOH)8-SA/CuTAPc-CS bipolar membranes(BPM).The ion exchange capacity and hydrogen ion transmigration rate of the CuPc(COOH)8-SA cation exchange membrane,and the ion exchange capacity and hydroxide ion transmigration rate of the CuTAPc-CS anion exchange membrane were increased.The water splitting rate at the interl... |
| |
| Keywords: | Copper octocarboxyphthalocyanine Copper tetraaminophthalocyanine Sodium alginate Chitosan Bipolar membrane |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
|
点击此处可从《高等学校化学学报》下载全文 |
|
