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Uniqueness for the BBGKY hierarchy for hard spheres in one dimension
Authors:Harold J. Raveché  Charles A. Stuart
Affiliation:(1) National Bureau of Standards, Washington, D.C.;(2) École Polytechnique Fédérale de Lausanne, Lausanne, Switzerland
Abstract:We prove that the stationary BBGKY hierarchy for an infinite system of hard spheres in one dimension has a unique solution for all densities, within a symmetry class that pertains to either a fluid array or to a perfect crystalline array. The solution is shown to correspond to the uniform fluid, which is the only equilibrium state of the infinite system. The proof is subject to the recursion relation for the correlation functions found by Salsburg, Zwanzig, and Kirkwood, which we show exactly reduces the infinite hierarchy to a pair of coupled equations. A brief discussion is given of the existence of multiple solutions of an approximate BBGKY equation.
Keywords:Solution of BBGKY hierarchy  one-dimensional hard spheres  correlation functions  uniqueness
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