| SDBS与HA缓蚀剂复配的实验与理论研究 |
| |
| 引用本文： | 胡松青,于立军,燕友果,张军,任振甲,提阳. SDBS与HA缓蚀剂复配的实验与理论研究[J]. 物理化学学报, 2011, 27(2): 275-280. DOI: 10.3866/PKU.WHXB20110215 |
| |
| 作者姓名： | 胡松青 于立军 燕友果 张军 任振甲 提阳 |
| |
| 作者单位： | College of Physics Science and Technology, China University of Petroleum, Dongying 257061, Shandong Province, P. R. China |
| |
| 基金项目： | 中国石油中青年创新基金(07E1021); 山东省自然科学基金(Y2006B35)资助项目~~ |
| |
| 摘 要： | 通过静态失重法研究了十二烷基苯磺酸钠(SDBS)与六亚甲基四胺(HA)在盐酸溶液中对Q235钢的协同缓蚀效应, 并采用分子动力学模拟从缓蚀剂膜抑制腐蚀粒子扩散的角度对其缓蚀机理进行分析. 结果显示: SDBS和HA单独使用时, 最高缓蚀效率分别为82.82%和79.46%, 复配后最高缓蚀效率可达到92.78%; 与两种缓蚀剂单独使用时相比, SDBS与HA复配后缓蚀剂膜体系中的自由空间明显下降, 削弱了膜内缓蚀剂分子的自扩散能力, 腐蚀粒子在缓蚀剂膜携带下的被动迁移也随之减弱; SDBS与HA复配能更有效抑制腐蚀粒子在缓蚀剂膜中的扩散, 也就是说复配后的缓蚀剂具有更好的缓蚀性能.
|
| 关 键 词： | 十二烷基苯磺酸钠 六亚甲基四胺 失重法 分子动力学模拟 扩散系数 |
| 收稿时间： | 2010-06-23 |
| 修稿时间： | 2010-12-28 |
Experimental and Theoretical Study of the Synergistic Inhibitive Effect of SOBS and HA |
| |
| HU Song-Qing,YU Li-Jun,YAN You-Guo,ZHANG Jun,REN Zhen-Jia,TI Yang. Experimental and Theoretical Study of the Synergistic Inhibitive Effect of SOBS and HA[J]. Acta Physico-Chimica Sinica, 2011, 27(2): 275-280. DOI: 10.3866/PKU.WHXB20110215 |
| |
| Authors: | HU Song-Qing YU Li-Jun YAN You-Guo ZHANG Jun REN Zhen-Jia TI Yang |
| |
| Affiliation: | College of Physics Science and Technology, China University of Petroleum, Dongying 257061, Shandong Province, P. R. China |
| |
| Abstract: | The synergistic inhibitive effect of sodium dodecylbenzene sulfonate(SDBS) and hexamethylene tetramine(HA) toward Q235 steel in hydrochloric acid was investigated by the static weight loss method.We also studied the inhibition mechanism by molecular dynamics simulations with regard to the inhibition of aggressive particle diffusion by inhibitor membranes.SDBS and HA were found to have individual inhibition efficiencies of 82.82% and 79.46%,respectively.These inhibition efficiencies increased to an efficienc... |
| |
| Keywords: | Sodium dodecylbenzene sulfonate Hexamethylene tetramine Weight loss method Molecular dynamics simulation Diffusion coefficient |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《物理化学学报》浏览原始摘要信息 |
|
点击此处可从《物理化学学报》下载全文 |
|
