Kinetics of oxidation of adonitol by manganese(III) pyrophosphate |
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| Authors: | A. G. Fadnis and S. K. Kulshrestha |
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| Affiliation: | (1) Department of Chemistry, Govt. Science College, 474 002 Gwalior, (M. P.), India |
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| Abstract: | Adonitol is oxidized to ribose by Mn(III) pyrophosphate under the conditions [adonitol]  [Mn(III)]. The oxidation rate is first order with respect to both oxidatn and substrate and decreases inversly with [pyrophosphate]free. Thermodynamic parameters are reported and a suitable mechanism involving free radicals is proposed.
                     (III)    [] [Mn(III)].     ,  - [].   - .
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