Kinetics of the Volume and Surface Reactions in the Phase-Transfer Catalytic Aminolysis of 4-Nitrophenyl Acetate |
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| Authors: | Vakhitova L N Popov A F Burdina Ya F Savelova V A Belousova I A |
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| Institution: | (1) L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, 70 R. Luxemburg Vul., 83114 Donets'k, Ukraine |
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| Abstract: | It was shown that a distribution-type kinetic model can be used to describe the mechanism of the phase-transfer catalytic aminolysis of 4-nitrophenyl acetate with potassium glycinate in chlorobenzene with 18-crown-6 as catalyst. A quantitative assessment was made of the contributions from the reactions in the volume and at the interface in the solid/liquid system. |
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| Keywords: | phase-transfer catalysis crown ether potassium glycinate distribution kinetic model |
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