Coordination polymers undergoing spin crossover and reversible ligand exchange in the solid |
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Authors: | Galet Ana Muñoz M Carmen Real José Antonio |
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Affiliation: | Departament de Física Aplicada, Universitat Politécnica de València, Camino de Vera s/n, 46022, Valencia, Spain. |
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Abstract: | Here we report the synthesis and characterisation of a polymer made up of a system of parallel 2-D grids of Fe(II) ions linked by [Au(CN)2]- bridges and its transformation into a new system of three interpenetrated 3-D coordination open frameworks with the NbO topology. Reversibility of this crystal-to-crystal transformation is evidenced by X-ray crystallographic data and from their spin crossover properties. |
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