Resonance fluorescence of gaseous chlorine excited with a single longitudinal mode argon ion laser

Resonance fluorescence spectra of gaseous chlorine, excited with a high power single longitudinal mode argon ion laser which was tuned through the lasing profiles of the 4880-, 4965-, 5017-, and 5145-Å lines, were studied. Five progressions of fluorescence lines were found and assigned as the fluorescence of ³⁵Cl³⁵Cl and ³⁷Cl³⁷Cl isotopic molecules resonantly excited from v = 0 and 1 levels of the X¹Σ state to the B³Π state. The fluorescence line positions agreed with those of the theoretical calculation within 0.2 cm^?1. The fluorescence intensities were very weak due to the extremely small transition probability between the B³Π and the X¹Σ states.