Vibrational spectra and analyses of MFe(CO)4 (M = Cd,Hg) |
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| Authors: | AE Mauro O Sala Y Hase |
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| Institution: | Instituto de Química de Araraquara, UNESPBrasil;Instituto de Química de Säo Paulo, USPBrasil;Instituto de Química de Campinas. UNICAMPBrasil |
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| Abstract: | The IR and Raman spectra of the compounds CdFe(CO)4 and HgFe(CO)4, are reported and assigned using C2v, local symmetry around the iron atom; vibrational analyses of the spectra have also been carried out. The spectroscopic data obtained indicate that the compounds are probably polymers with a centre of symmetry and an octahedral configuration about the iron atom in accordance with X-ray structural results. |
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| Keywords: | To whom correspondence should be addressed: Institute de Química de Araraquara UNESP C P 174 14800 Araraquara SP Brasil |
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