| 对称排列的咔唑基树状分子的合成及其光物理性能和电化学性能(英文) |
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| 引用本文： | 朱志博,蔡玉春.对称排列的咔唑基树状分子的合成及其光物理性能和电化学性能(英文)[J].化学研究,2010,21(2):38-41. |
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| 作者姓名： | 朱志博 蔡玉春 |
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| 作者单位： | 南方医科大学,药学院,广东,广州,510315 |
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| 基金项目： | Foundation item：Technology Project of Guangdong Province（7300449）. |
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| 摘 要： | 采用乌尔曼缩合反应合成了新型的咔唑基树状分子;利用核磁共振谱仪(1HNMR,13CNMR)和飞行时间质谱仪(MALDI-TOF-Mass)对其进行了表征;并评价了树状分子的荧光性能和电化学性能.结果表明,所合成的咔唑基树状化合物在394nm处发蓝光,同时具有低的HOMO能级.
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| 关 键 词： | 咔唑 树状分子 合成 荧光 电化学性能 |
Synthesis and Optical and Electrochemical Properties of Symmetrically Arranged Carbazole Dendrimers |
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| ZHU Zhi-bo,CAI Yu-Chun.Synthesis and Optical and Electrochemical Properties of Symmetrically Arranged Carbazole Dendrimers[J].Chemical Research,2010,21(2):38-41. |
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| Authors: | ZHU Zhi-bo CAI Yu-Chun |
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| Institution: | (School of Pharmaceutical Sciences, Southern Medical University, Guangzhou 510315, Guangdong , China) |
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| Abstract: | One novel carbazole dendritic compound was synthesized by using modified Ullmann condensation reaction. The product was characterized by means of nuclear magnetic resonance (1H NMR, 13C NMR) spectroscopy and time-of-flight mass spectrometry (MALDI-TOF-Mass). At the same time, the luminescent property and electronic property of the product were evaluated. Results show that the synthetic compound exhibits blue fluorescence at a maximum wavelength of 394 nm and low energy level of highest occupied molecular orbital (HOMO) as well. |
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| Keywords: | carbazole dendritic compound synthesis fluorescence electrochemical property |
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