The kirkwood-salsburg equations for random continuum percolation |
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Authors: | James A Given George Stell |
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Institution: | (1) Department of Chemistry, State University of New York, 11794 Stony Brook, New York |
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Abstract: | We develop two different hierarchies of Kirkwood-Salsburg equations for the connectedness functions of random continuum percolation. These equations are derived by writing the Kirkwood-Salsburg equations for the distribution functions of thes-state continuum Potts model (CPM), taking thes1 limit, and forming appropriate linear combinations. The first hierarchy is satisfied by a subset of the connectedness functions used in previous studies. It gives rigorous, low-order bounds for the mean number of clusters n
c
and the two-point connectedness function. The second hierarchy is a closed set of equations satisfied by the generalized blocking functions, each of which is defined by the probability that a given set of connections between particles is absent. These auxiliary functions are shown to be a natural basis for calculating the properties of continuum percolation models. They are the objects naturally occurring in integral equations for percolation theory. Also, the standard connectedness functions can be written as linear combinations of them. Using our second Kirkwood-Salsburg hierarchy, we show the existence of an infinite sequence of rigorous, upper and lower bounds for all the quantities describing random percolation, including the mean cluster size and mean number of clusters. These equations also provide a rigorous lower bound for the radius of convergence of the virial series for the mean number of clusters. Most of the results obtained here can be readily extended to percolation models on lattices, and to models with positive (repulsive) pair potentials. |
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Keywords: | Kirkwood-Salsburg equations continuum percolation connectedness functions radius of convergence rigorous bounds continuum Potts model |
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