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Synthesis and Solution Properties of Loose Polymer Brushes Having Polyimide Backbone and Methylmethacrylate Side Chains
Authors:Anna Krasova  Elena Belyaeva  Elena Tarabukina  Alexander Filippov  Tamara Meleshko  Dmitry Ilgach  Natalia Bogorad  Alexander Yakimansky
Institution:Institute of Macromolecular Compounds of Russian Academy of Sciences, Bolshoy pr., 31, Saint-Petersburg 199004, Russia
Abstract:Summary: Graft-copolymers with polyimide backbone and PMMA side chains are synthesized by ATRP of methylmethacrylate on the polyimide macroinitiator. The obtained copolymers, macroinitiator, and cleaved side chains are investigated by 1H NMR, SEC, static and dynamic light scattering, sedimentation, and viscosimetry in solutions. The synthesized copolymer is relatively loose polymer brushes: the average distance between grafted PMMA chains is ∼11 nm (4 repeat units of the backbone). The hydrodynamic and conformational characteristics of graft-copolymers change on passage from ethylacetate to chloroform due to difference in the thermodynamic quality of the solvents with respect to the copolymer components. The backbone is characterized more extended conformation than individual polyimide macromolecule.
Keywords:atom transfer radical polymerization  conformational analysis  graft copolymers  polyimide macroinitiator  solution properties
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