ChemInform Abstract: Quantum‐Chemical Calculations and IR Spectra of the (F2)MF2 Molecules (M: B,Al, Ga,In, Tl) in Solid Matrices: A New Class of Very High Electron Affinity Neutral Molecules.
The new class of neutral adduct molecules (F2)MF2 (M: B, Al, Ga, In, Tl) forms by reaction of laser‐ablated group 13 metal atoms with F2 in excess Ar and Ne during condensation at 5 K.