Highly diastereoselective nucleophilic addition reactions of masked acyl cyanide reagents to tert-butanesulfiminides |
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Affiliation: | Division of Pharmaceutical Chemistry, Institute of Health Biosciences, Graduate School of The University of Tokushima, 1-78, Sho-machi, Tokushima 770-8505, Japan |
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Abstract: | Addition reactions of dicyanomethyl tert-butyldimethylsilyl ether (H–MAC–TBS) to optically active tert-butanesulfinimides afforded α-amino acid precursors in excellent yields and with high diastereoselectivities. |
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