Enantioselective allylic substitution of Morita–Baylis–Hillman adducts catalyzed by planar chiral [2.2]paracyclophane monophosphines |
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Institution: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China |
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Abstract: | Planar chiral 2,2]cyclophane monophosphines are efficient catalyst in the reaction of Morita–Baylis–Hillman adducts with phthalimide. The corresponding allylic substituted products were afforded in high yields and in good to moderate ee. |
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