Tetrathiafulvalene–oxazoline ligands in the iridium catalyzed enantioselective hydrogenation of arylimines |
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| Institution: | 1. Laboratoire de Chimie, Ingénierie Moléculaire et Matériaux d’Angers, UMR 6200, 2 Bd Lavoisier, 49045 Angers Cedex, France;2. Laboratoire de Catalyse de Lille, UMR 8010, ENSCL, BP 90108, 59652 Villeneuve d’Ascq Cedex, France |
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| Abstract: | Cationic iridium complexes based on enantiomerically pure tetrathiafulvalene–oxazoline ligands have been used in the asymmetric hydrogenation of N-(phenylethylidene)aniline. Complete conversions with ee’s up to 68% could be reached in the case of the TTF–phosphinooxazoline (TTF–PHOX) ligands. |
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