Synthesis and odor description of optically active cyclopropanated analogues of geraniol,nerol, nor-leaf alcohol,and matsutake alcohol |
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Affiliation: | Laboratory of Applied Bioorganic Chemistry, Division of Bioscience and Biotechnology for Future Bioindustry, Graduate School of Agricultural Science, Tohoku University, Tsutsumidori-Amamiya, Aoba-ku, Sendai 981-8555, Japan |
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Abstract: | Both enantiomers of cyclopropanated analogues of geraniol, nerol, nor-leaf alcohol, and matsutake alcohol were synthesized and their odor properties evaluated. Odor characters in enantiomeric pairs were similar in the geraniol series. The (+)-(2R,3S)-nerol derivative showed various odor aspects. From the results of nor-leaf alcohol derivatives, an interaction between the (2-re,3-re)-face of nor-leaf alcohol and the human olfactory receptor was suggested. The odor of (3R)-matsutake alcohol derivative was superior to the enantiomer. |
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