Gamma irradiation of polyester films |
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Institution: | 1. State Key Laboratory of Rare Earth Resource Utilization, ERC for the Separation and Purification of REs and Thorium, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;2. University of Chinese Academy of Sciences, Beijing 100049, China |
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Abstract: | Irradiation in air of several thermoplastic aromatic polyesters was carried out in order to investigate changes in characteristic properties. Polymers are irradiated at high doses, until 1 MGy, and no drastic changes seem to emerge. Dielectric and resistance measurements are carried out in order to evaluate changes in electrical insulation property; moreover, nanoholes dimensions, analyzed by positron spectroscopy, are measured in pristine and irradiated polyesters. The study shows good durability of this kind of polyesters, due to the aromatic rings able to stabilize the polymeric chains towards ionizing radiations and able to preserve the original structural, electrical and permeability properties. |
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