Highly efficient and enantioselective cyclopropanation of styrene with diazoacetates using a new copper-(Schiff-base) catalyst |
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Institution: | 1. Department of Chemistry, Sharif University of Technology, Tehran 11155-3615, Iran;2. Faculty of Chemistry, Shahid Beheshti University, G. C., Evin, Tehran 1983963113, Iran |
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Abstract: | A new copper-(Schiff-base) complex, derived from (S)-2-amino-1,1-di(3,5-di-t-butylphenyl)propanol, 2-hydroxy-5-nitrobenzaldehyde and copper acetate monohydrate, was used as an efficient catalyst for the cyclopropanation of styrene with diazoacetates, affording ees of up to 98%. |
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