Stereoselective synthesis of highly oxygenated cyclohexanes through a [3+3] annulation approach |
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| Institution: | 1. Faculty of Chemistry, University of Łódź, 91403 Łódź, Poland;2. Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, 90363 Łódź, Poland;3. Department of Chemistry, Middle Tennessee State University, Murfreesboro 37132, TN, USA |
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| Abstract: | The synthesis of highly oxygenated cyclohexanes has been achieved through a Michael–Wittig protocol via a 3+3] annulation of the enal that is derived from 2,3-O-isopropylidene-(R)-glyceraldehyde. The γ-alkoxy enal system is responsible for the stereoselectivity. |
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