An efficient phosphorus-containing oxazoline ligand derived from cis-2-amino-3,3-dimethyl-1-indanol: application to the palladium-catalyzed asymmetric Heck reaction |
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| Affiliation: | 1. Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo Hongo, Bunkyo-ku, Tokyo 113-8656, Japan;2. Department of Integrated Biosciences, Graduate School of Frontier Sciences, The University of Tokyo Hongo, Bunkyo-ku, Tokyo 113-8656, Japan;1. Lee Gil Ya Cancer and Diabetes Institute, Gachon University, Yeonsu-gu, Incheon 21999, Republic of Korea;2. College of Pharmacy, Gachon Institute of Pharmaceutical Science, Gachon University, Yeonsu-gu, Incheon 21936, Republic of Korea;3. College of Pharmacy, Mokpo National University, Muan-gun, Jeonnam 58554, Republic of Korea;4. Kwang Dong Pharmaceutical Co., Ltd., Seocho-gu, Seoul 06650, Republic of Korea;5. Gachon Medical Research Institute, Gil Hospital, Namdong-gu, Incheon 21565, Republic of Korea;1. School of Mathematics and Statistics, Southwest University, Chongqing 400715, PR China;2. Department of Mathematics and Statistics, Chongqing University, Chongqing 401331, PR China;1. Dept. of CSIE, National Taiwan University of Science and Technology, Taipei, Taiwan;2. Research Center for IT Innovation (CITI), Academia Sinica, Taipei, Taiwan |
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| Abstract: | Enantiopure 2-[2-(diphenylphosphino)phenyl]oxazoline, derived from a non-natural chiral aminoalcohol, cis-2-amino-3,3-dimethyl-1-indanol, was found to be an efficient ligand for the palladium-catalyzed asymmetric Heck reaction. |
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