New,highly efficient syntheses of rac-, (R)- and (S)-4-hydroxy-2-cyclohexenone |
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| Affiliation: | 1. Department of Chemistry, Indiana University, Bloomington, IN 47405, United States;2. Department of Computer Science and Informatics, Indiana University, Bloomington, IN 47405, United States;3. Buck Institute for Research on Aging, Novato, CA 94945, United States;4. Department of Biology, Indiana University, Bloomington, IN 47405, United States;1. Jiangsu Key Laboratory of Drug Design and Optimization, China Pharmaceutical University, Nanjing 210009, China;2. State Key Laboratory of Natural Medicines, China Pharmaceutical University, Nanjing 210009, China;3. Department of Medicinal Chemistry, School of Pharmacy, China Pharmaceutical University, Nanjing 210009, China;4. Department of Organic Chemistry, School of Science, China Pharmaceutical University, Nanjing 210009, China;1. Laboratory of Bioorganic Chemistry and Chemical Biology, Center for Nanotechnology, Heisenbergstraße 11, 48149 Münster, Germany;2. Laboratorium für Organische und Bioorganische Chemie, Institut für Chemie neuer Materialien, Universität Osnabrück, Barbarastraße 7, 49069 Osnabrück, Germany;1. Green Manufacturing 3Rs R&D Group, Korea Institute of Industrial Technology, Ulsan 681-310, Republic of Korea;2. School of Materials Science Engineering, KIST-UNIST-Ulsan Center for Convergent Materials, Ulsan National Institute of Science and Technology (UNIST), Ulsan 689-798, Republic of Korea;3. School of Civil, Environmental, and Architectural Engineering, Korea University, 5 Anam-dong, Seoul 136-701, Republic of Korea |
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| Abstract: | Both enantiomers of 4-hydroxy-2-cyclohexenone have been synthesised from chiral p-benzoquinone equivalents through very short and simple sequences in good overall yields. |
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