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Enantioselective reduction of aromatic ketones catalysed by chiral ruthenium(II) complexes |
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| Institution: | 1. CAS Key Laboratory of Advanced Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026, PR China;2. Department of Energy Conversion and Storage, Technical University of Denmark, Roskilde DK-4000, Denmark |
| Abstract: | The catalytic enantioselective reduction of aromatic ketones in 2-propanol is carried out by using ruthenium(II) complexes prepared from Ru(p-cymene)Cl2]2 and a variety of chiral diamines and β-aminoalcohols derived from α-amino acids. Good conversions (>99%) and enantioselectivities (=96%) are observed under mild reaction conditions. |
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