Hydrothermal synthesis of molybdenum oxide based materials: strategy and structural chemistry |
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| Authors: | Michailovski Alexej Patzke Greta R |
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| Institution: | Department of Chemistry and Applied Biosciences, ETH Zürich, Wolfgang-Pauli-Str. 10, 8093 Zürich, Switzerland. |
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| Abstract: | The preparative flexibility of hydrothermal syntheses needs to be systemised for exploring complex structure-synthesis relationships and morphology control options in materials chemistry. This is demonstrated for the targeted hydrothermal preparation of molybdenum oxide materials: firstly, in situ studies were employed for the efficient production of MoO(3) nanofibres. Furthermore, ionic substances as structure-directing tools brought forward a new class of fluorinated polyoxomolybdates. |
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| Keywords: | hydrothermal synthesis in situ spectroscopy molybdenum oxide nanostructures polyoxometalates |
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