Synthese und Eigenschaften von Bis(Dimethylarsino)-aminen |
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| Authors: | F. Kober |
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| Abstract: | Synthesis and Properties of Bis(dimethylarsino) Amines Primary amines react with cacodyl halides (CH3)2AsX (X = Cl, J) under formation of Bis(dimethylarsino)amines RN[As(CH3)2]2. Nine amines were prepared. The compounds were characterized by IR, 1H-nmr and mass-spectroscopy. In the reactions with acid molecules cleavage of the As? N bond was observed. Formation of amine RNH2 or ammoniumsalt (RNH3)X and cacodyl derivates took place in all cases. The reactions of the arsinoamines with some carbonyles are reported. |
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