Palladium-catalyzed relay C–H functionalization to construct novel hybrid-arylcyclophosphorus ligand precursors |
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作者姓名: | Juan Wang Peng-Bo Bai Shang-Dong Yang |
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作者单位: | 1. State Key Laboratory of Applied Organic Chemistry, Lanzhou University;2. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences |
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摘 要: | A new relay C–H functionalization of di([1,1’-biphenyl]-2-yl)phosphine oxide to obtain esterified and hydroxylated products with different hypervalent iodines as oxidants under palladium catalysis is disclosed.This reaction provides a more effective and concise strategy for the synthesis of novel structural hybrid-arylcyclophosphorus ligand precursors with a wide range of substrates and good functional group tolerance.
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收稿时间: | 2021-07-16 |
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