| Triphenylamines consisting of bulky 3,5-di–tert–butyl–4-anisyl group:Synthesis,redox properties and their radical cation species |
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| 作者姓名： | Manfei Zhou Lijun Mao Yan-Fei Niu Xiao-Li Zhao Xueliang Shi Hai-Bo Yang |
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| 作者单位： | Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University |
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| 基金项目： | financially supported by the National Natural Science Foundation of China (Nos. 22071061 and 52003081)； |
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| 摘 要： | Triphenylamine(TPA) derivatives have been widely used as useful building blocks for diverse functional materials because of their excellent redox activity. Most of the molecular structures of TPA-based organic functional materials contain 4-anisyl groups, which on one hand could reduce their oxidation potential and on the other hand significantly delocalize the spin density of the resultant TPA radical cation species and enhance their stability. However, molecular-level investigation of the redo...
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| 收稿时间： | 17 August 2021 |
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