| XPS SHAKE-UP AND HMO CALCULATION ON SOME CONJUGATED RING CARBON-HYDROGEN COMPOUNDS |
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| 引用本文： | 李宗和,于鷃,王殿勋,徐广智. XPS SHAKE-UP AND HMO CALCULATION ON SOME CONJUGATED RING CARBON-HYDROGEN COMPOUNDS[J]. 中国科学B辑(英文版), 1989, 0(8) |
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| 作者姓名： | 李宗和 于鷃 王殿勋 徐广智 |
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| 作者单位： | Department of Chemistry，Beijing Normal University，Department of Chemistry，Beijing Normal University，Institute of Chemistry，Academia Sinica. Beijing，Institute of Chemistry，Academia Sinica. Beijing |
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| 摘 要： | XPS shake-up satellite peaks (XPS shake-up) and HMO calculations of some conjugatedring carbon-hydrogen compounds have been reported. The shake-up spacing and probabilityusing HMO calculation accord with XPS experimental results. The relation between shake-up transition of the excited atom and its chemical activity, namely, the order of its atomicfree valence, has been established.
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XPS SHAKE-UP AND HMO CALCULATION ON SOME CONJUGATED RING CARBON-HYDROGEN COMPOUNDS |
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| LI ZHONG-HE,YU YAN,WANG DIAN--XUN,XU GUANG-ZHI. XPS SHAKE-UP AND HMO CALCULATION ON SOME CONJUGATED RING CARBON-HYDROGEN COMPOUNDS[J]. Science in China(Chemistry), 1989, 0(8) |
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| Authors: | LI ZHONG-HE YU YAN WANG DIAN--XUN XU GUANG-ZHI |
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| Affiliation: | LI ZHONG-HE,YU YAN,WANG DIAN--XUN,XU GUANG-ZHI Department of Chemistry,Beijing Normal University Institute of Chemistry,Academia Sinica. Beijing |
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| Abstract: | XPS shake-up satellite peaks (XPS shake-up) and HMO calculations of some conjugatedring carbon-hydrogen compounds have been reported. The shake-up spacing and probabilityusing HMO calculation accord with XPS experimental results. The relation between shake-up transition of the excited atom and its chemical activity, namely, the order of its atomicfree valence, has been established. |
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| Keywords: | XPS shake-up HMO calculation conjugated ring carbon-hydrogen compounds |
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