The Synthesis and Crystal Structure of 5-Methyl-1-(1-naphthyl)-1,2,3-triazol-4-carboxyl Acid |
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| Authors: | Shi-Qiang Liu Bin Quan Hong-Ru Dong Heng-Shan Dong |
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| Institution: | (1) State Key Laboratory of Applied Organic Chemistry, Institute of Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu, 730000, People’s Republic of China;(2) College of Science and Engineering, Gansu Association University, Lanzhou, Gansu, 730000, China |
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| Abstract: | Abstract 5-Methyl-1-(1-naphthyl)-1,2,3-triazol-4-carboxyl acid 3
was synthesized from 1-aminonaphthalene. The yielded product 3 was investigated
with X-ray crystallographic, NMR, MS and IR techniques. Compound 3,
C14H11N3O2, Mr = 253.26,
crystallizes in the orthorhombic space group Pbca with unit cell parameters a = 10.068(2), b = 12.353(2), c = 20.102(4)
?, V = 2500.1(8) ?3, Z = 8, Dx = 1.346 Mgm-3. The final R was
0.0474. The molecular packing is stabilized by intermolecular O–H···N interactions.
Index Abstract 5-Methyl-1-(1-naphthyl)-1,2,3-triazol-4-carboxyl acid 3 was synthesized from 1-aminonaphthalene. The yielded product 3
was investigated with X-ray crystallographic, NMR, MS and IR techniques. Compound 3, C14H11N3O2, Mr = 253.26,
crystallizes in the orthorhombic space group Pbca with unit cell parameters a = 10.068(2), b = 12.353(2), c = 20.102(4) ?,
α = β = γ = 90.00o. V = 2,500.1(8) ?3, Z = 8, Dx = 1.346 Mgm−3. The final R was 0.0474. The molecular packing is stabilized by
intermolecular O–H···N interactions.
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| Keywords: | Crystal structure 1 2 3-Triazol-4-carboxyl acid 5-Methyl-1-(1-naphthyl)-1 2 3-triazol-4-carboxyl acid H-bond Synthesis |
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