Reactions of N-heterocyclic carbenes (NHCs) with one-electron oxidants: possible formation of a carbene cation radical |
| |
| Authors: | Ramnial Taramatee McKenzie Iain Gorodetsky Brian Tsang Emily M W Clyburne Jason A C |
| |
| Affiliation: | Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, BC V5A 1S6, Canada. |
| |
| Abstract: | One-electron oxidation of N-heterocyclic carbenes (NHCs) has been carried out using oxidising agents such as tetracyanoethylene (TCNE) and ferrocenium [Cp(2)Fe](+); the formation of carbene radical cations is postulated. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
